Login Register Cart 0
Generic placeholder image

Recent Patents on Nanotechnology

Editor-in-Chief

ISSN (Print): 1872-2105
ISSN (Online): 2212-4020

Back
Journal Home About Journal Editorial Board Journal Insight Current Issue Volumes/Issues
Subscribe
Research Article

Investigation of Electromagnetic Wave Absorption Properties of Ni-Co and MWCNT Nanocomposites

Author(s): Majid Ebrahimzadeh*, Abdolrasoul Gharaati, Alireza Jangjoo and Hamed Rezazadeh

Volume 18, Issue 4, 2024

Published on: 21 December, 2022

Page: [519 - 526] Pages: 8

DOI: 10.2174/1872210517666221118110054

Price: $65

Abstract

Background: In recent years, severe electromagnetic interference among electronic devices has been caused by the unprecedented growth of communication systems. Therefore, microwave absorbing materials are required to relieve these problems by absorbing the unwanted microwave. In the design of microwave absorbers, magnetic nanomaterials have to be used as fine particles dispersed in an insulating matrix. Besides the intrinsic properties of these materials, the structure and morphology are also crucial to the microwave absorption performance of the composite. In this study, Ni-Co- MWCNT composites were synthesized, and the changes in electric permittivity, magnetic permeability, and reflectance loss of the samples were evaluated at frequencies of 2 to 18 GHz.

Methods: Nickel-Cobalt-Multi Wall Carbon Nanotubes (MWCNT) composites were successfully synthesized by the co-precipitation chemical method. The structural, morphological, and magnetic properties of the samples were characterized and investigated by X-ray diffractometer (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Vibrating Sample Magnetometer (VSM), and Vector Network Analyzer (VNA).

Results: The results revealed that the Ni-Co-MWCNT composite has the highest electromagnetic wave absorption rate with a reflectance loss of -70.22 dB at a frequency of 10.12 GHz with a thickness of 1.8 mm. The adequate absorption bandwidth (RL <-10 dB) was 6.9 GHz at the high-frequency region, exhibiting excellent microwave absorbing properties as a good microwave absorber patent.

Conclusion: Based on this study, it can be argued that the Ni-Co-MWCNT composite can be a good candidate for making light absorbers of radar waves at frequencies 2- 18 GHz.

Keywords: Microwave absorber, electromagnetic waves, multiwall carbon nanotube, nickel, cobalt, absorption properties.

« Previous Next »
Graphical Abstract

[1]
Cui X, Liang X, Liu W, Gu W, Ji G, Du Y. Stable microwave absorber derived from 1D customized heterogeneous structures of Fe3N@C. Chem Eng J 2020; 381: 122589.
[http://dx.doi.org/10.1016/j.cej.2019.122589]
[2]
Gu W, Sheng J, Huang Q, Wang G, Chen J, Ji G. Environmentally friendly and multifunctional shaddock peel-based carbon aerogel for thermal-insulation and microwave absorption. Nano-Micro Lett 2021; 13(1): 102.
[http://dx.doi.org/10.1007/s40820-021-00635-1] [PMID: 34138342]
[3]
Gharaati A, Ebrahimzadeh M. Enhanced microwave absorption properties of FeCo@TiO2 core-shell nanoparticles. Curr Nanosci 2018; 15(2): 163-8.
[http://dx.doi.org/10.2174/1573413714666180621110928]
[4]
Yan J, Huang Y, Zhang X, et al. MoS2-decorated/integrated carbon fiber: phase engineering well-regulated microwave absorber. Nano-Micro Lett 2021; 13(1): 114.
[http://dx.doi.org/10.1007/s40820-021-00646-y]
[5]
Zhang H, Shi C, Jia Z, et al. FeNi nanoparticles embedded reduced graphene/nitrogen-doped carbon composites towards the ultra-wideband electromagnetic wave absorption. J Colloid Interface Sci 2021; 584: 382-94.
[http://dx.doi.org/10.1016/j.jcis.2020.09.122] [PMID: 33080500]
[6]
Wei Y, Shi Y, Zhang X, et al. Preparation of black titanium monoxide nanoparticles and their potential in electromagnetic wave absorption. Adv Powder Technol 2020; 31(8): 3458-64.
[http://dx.doi.org/10.1016/j.apt.2020.06.032]
[7]
Ghaforyan H, Ebrahimzadeh M, Ghaffary T, Rezazadeh H, Jahromi ZS. Microwave absorbing properties of Ni nanowires grown in nanoporous anodic alumina templates. Zhongguo Wuli Xuekan 2014; 52(1): 233-8.
[8]
Guo Y, Qiu H, Ruan K, Zhang Y, Gu J. Hierarchically multifunctional polyimide composite films with strongly enhanced thermal conductivity. Nano-Micro Lett 2022; 14(1): 26.
[http://dx.doi.org/10.1007/s40820-021-00767-4] [PMID: 34890012]
[9]
Mandal D, Gorai A, Mandal K. Electromagnetic wave trapping in NiFe2O4 nano-hollow spheres: An efficient microwave absorber. J Magn Magn Mater 2019; 485: 43-8.
[http://dx.doi.org/10.1016/j.jmmm.2019.04.033]
[10]
Zhang Y, Gao S, Xing H, Li H. In situ carbon nanotubes encapsulated metal Nickel as high-performance microwave absorber from Ni-Zn Metal-Organic framework derivative. J Alloys Compd 2019; 801: 609-18.
[http://dx.doi.org/10.1016/j.jallcom.2019.06.164]
[11]
Zhang Y, Gao S, Xing H. Reduced graphene oxide wrapped cube-like ZnSnO3: As a high-performance microwave absorber. J Alloys Compd 2019; 777: 544-53.
[http://dx.doi.org/10.1016/j.jallcom.2018.10.378]
[12]
Wang Y, Di X, Gao X, Wu X, Wang P. Rational construction of Co@C polyhedrons covalently-grafted on magnetic graphene as a superior microwave absorber. J Alloys Compd 2020; 843: 156031.
[http://dx.doi.org/10.1016/j.jallcom.2020.156031]
[13]
Shi X, You W, Zhao Y, Li X, Shao Z, Che R. Multi-scale magnetic coupling of Fe@SiO2 @C–Ni yolk@triple-shell microspheres for broadband microwave absorption. Nanoscale 2019; 11(37): 17270-6.
[http://dx.doi.org/10.1039/C9NR06629B] [PMID: 31528905]
[14]
Zhang X, Shi Y, Xu J, et al. Identification of the intrinsic dielectric properties of metal single atoms for electromagnetic wave absorption. Nano-Micro Lett 2022; 14(1): 27.
[http://dx.doi.org/10.1007/s40820-021-00773-6] [PMID: 34894293]
[15]
Wang L, Yu X, Li X, Zhang J, Wang M, Che R. MOF-derived yolk-shell Ni@C@ZnO Schottky contact structure for enhanced microwave absorption. Chem Eng J 2020; 383: 123099.
[http://dx.doi.org/10.1016/j.cej.2019.123099]
[16]
Quan L, Qin FX, Li YH, et al. Magnetic graphene enabled tunable microwave absorber via thermal control. Nanotechnology 2018; 29(24): 245706.
[http://dx.doi.org/10.1088/1361-6528/aabaae] [PMID: 29595518]
[17]
Zhang Q, Du Z, Huang X, et al. Tunable microwave absorptivity in reduced graphene oxide functionalized with Fe3O4 nanorods. Appl Surf Sci 2019; 473: 706-14.
[http://dx.doi.org/10.1016/j.apsusc.2018.12.130]
[18]
Kuang D, Hou L, Wang S, et al. Facile synthesis of Fe/Fe3C-C core-shell nanoparticles as a high-efficiency microwave absorber. Appl Surf Sci 2019; 493: 1083-9.
[http://dx.doi.org/10.1016/j.apsusc.2019.07.073]
[19]
Mayes E. Microwave absorbing structure. Pat. No. US6986942, 2006.
[20]
Shen GZ, Cheng GS, Cao Y, Xu Z. Preparation and microwave absorption of M type ferrite nanoparticle composites. Mater Sci Pol 2010; 28(1): 327-34.
[21]
Ivanovich ZG, Aleksandrovich KD. Anti-radar coating. Pat. No. RU2553284C2, 2015.
[22]
Mavig G. Shielding characterised by its physical form, e.g. granules, or shape of the material. Pat. No. CN102655812A, 2012.
[23]
Zhongbei S. Green industrial preparation method of ferroferric oxide/reduced graphene oxide and wave-absorbing resin composite material thereof. Pat. No. CN114539617A, 2022.
[24]
Nanjing University of Information Science and Technology. Composite wave-absorbing film material and preparation method thereof. Pat. No. CN114554822A, 2022.
[25]
CETC 29 Research Institute. Curved surface multilayer threedimensional interconnection structure. Pat. No. CN114552200A, 2022.
[26]
Toppan Inc. Electromagnetic wave attenuation film. Pat. No. JP2022082652A, 2022.
[27]
Chengdu University, With Y2Si2O7Si as a matrix 3N4/SiO2 Preparation method of/SiC-based microwave absorbing ceramic. Pat. No. CN114455943A, 2022.
[28]
Xiong Y, Luo H, Nie Y, et al. Synergistic effect of silica coated porous rodlike nickel ferrite and multiwalled carbon nanotube with improved electromagnetic wave absorption performance. J Alloys Compd 2019; 802: 364-72.
[http://dx.doi.org/10.1016/j.jallcom.2019.06.174]
[29]
Mo Z, Yang R, Lu D, et al. Lightweight, three-dimensional carbon Nanotube@TiO2 sponge with enhanced microwave absorption performance. Carbon 2019; 144: 433-9.
[http://dx.doi.org/10.1016/j.carbon.2018.12.064]
[30]
Yin Y, Liu X, Wei X, Yu R, Shui J. Porous CNTs/Co composite derived from zeolitic imidazolate framework: A lightweight, ultrathin, and highly efficient electromagnetic wave absorber. ACS Appl Mater Interfaces 2016; 8(50): 34686-98.
[http://dx.doi.org/10.1021/acsami.6b12178] [PMID: 27998119]
[31]
Fu M, Jiao Q, Zhao Y. Preparation of NiFe2O4 nanorod–graphene composites via an ionic liquid assisted one-step hydrothermal approach and their microwave absorbing properties. J Mater Chem A Mater Energy Sustain 2013; 1(18): 5577-86.
[http://dx.doi.org/10.1039/c3ta10402h]
[32]
Wang L, Huang Y, Li C, Chen J, Sun X. A facile one-pot method to synthesize a three-dimensional graphene@carbon nanotube composite as a high-efficiency microwave absorber. Phys Chem Chem Phys 2015; 17(3): 2228-34.
[http://dx.doi.org/10.1039/C4CP04745A] [PMID: 25485522]
[33]
Liu P, Huang Y, Yan J, Yang Y, Zhao Y. Construction of CuS nanoflakes vertically aligned on magnetically decorated graphene and their enhanced microwave absorption properties. ACS Appl Mater Interfaces 2016; 8(8): 5536-46.
[http://dx.doi.org/10.1021/acsami.5b10511] [PMID: 26886765]
[34]
Zhou C, Geng S, Xu X, et al. Lightweight hollow carbon nanospheres with tunable sizes towards enhancement in microwave absorption. Carbon 2016; 108: 234-41.
[http://dx.doi.org/10.1016/j.carbon.2016.07.015]
[35]
Zong M, Huang Y, Ding X, Zhang N, Qu C, Wang Y. One-step hydrothermal synthesis and microwave electromagnetic properties of RGO/NiFe2O4 composite. Ceram Int 2014; 40(5): 6821-8.
[http://dx.doi.org/10.1016/j.ceramint.2013.11.145]
[36]
Feng J, Hou Y, Wang Y, Li L. Synthesis of hierarchical ZnFe2O4@ SiO2@ RGO core–shell microspheres for enhanced electromagnetic wave absorption. ACS Appl Mater Interfaces 2017; 9(16): 14103-11.
[37]
Zhang XJ, Wang GS, Cao WQ, et al. Enhanced microwave absorption property of reduced graphene oxide (RGO)-MnFe2O4 nanocomposites and polyvinylidene fluoride. ACS Appl Mater Interfaces 2014; 6(10): 7471-8.
[http://dx.doi.org/10.1021/am500862g] [PMID: 24779487]
[38]
Wang Y, Guan H, Du S, Wang Y. A facile hydrothermal synthesis of MnO2 nanorod–reduced graphene oxide nanocomposites possessing excellent microwave absorption properties. RSC Advances 2015; 5(108): 88979-88.
[http://dx.doi.org/10.1039/C5RA15165A]
[39]
Liang H, Liu J, Zhang Y, Luo L, Wu H. Ultra-thin broccoli-like SCFs@TiO2 one-dimensional electromagnetic wave absorbing material. Compos, Part B Eng 2019; 178: 107507.
[http://dx.doi.org/10.1016/j.compositesb.2019.107507]
[40]
Zhang M, Ling H, Wang T, et al. An equivalent substitute strategy for constructing 3D ordered porous carbon foams and their electromagnetic attenuation mechanism. Nano-Micro Lett 2022; 14(1): 157.
[http://dx.doi.org/10.1007/s40820-022-00900-x] [PMID: 35916976]
[41]
Zhao L, Guo Y, Xie Y, et al. Construction of SiCNWS@NiCo2O4@PANI 1D hierarchical nanocomposites toward high-efficiency microwave absorption. Appl Surf Sci 2022; 592: 153324.
[http://dx.doi.org/10.1016/j.apsusc.2022.153324]
[42]
Li Z, Lin H, Xie Y, et al. Monodispersed Co@C nanoparticles anchored on reclaimed carbon black toward high-performance electromagnetic wave absorption. J Mater Sci Technol 2022; 124: 182-92.
[http://dx.doi.org/10.1016/j.jmst.2022.03.004]

Rights & Permissions Print Cite
Article Metrics
23
2
Wayfinder Image
© 2024 Bentham Science Publishers | Privacy Policy