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Recent Innovations in Chemical Engineering

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ISSN (Print): 2405-5204
ISSN (Online): 2405-5212

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Research Article

Photoelectrode FTO/ Anodized TiO2 Production and Characterization for Methylene Blue Affected Photoelectrochemical Decomposition

Author(s): Berrak Caliskan*, Enes Şayan and Hakan Kiziltas

Volume 17, Issue 2, 2024

Published on: 14 February, 2024

Page: [83 - 93] Pages: 11

DOI: 10.2174/0124055204284488240120053918

Price: $65

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Abstract

Background: The production of thin film TiO2 nanostructured systems for electrocatalytic, photocatalytic, and photoelectrocatalytic applications has been an essential topic in recent years. Due to the light-sensitive effect of TiO2, it can be produced by various methods and used as a photoelectrode to remove dye. Using magnetron sputtering, Ti thin films can be deposited on different substrates and converted into transparent TiO2 structures by electrochemical anodization.

Methods: In this study, the thin Ti film was produced using a magnetic spraying technique on the FTO substrate, and then an anodic TiO2 structure was obtained by the anodization technique. TiO2 films produced by the anodizing technique were used as a photoelectrode for the degradation of MB. The reactor contained 400 mL of 20 mg/L MB solution at 20 °C. The produced photoelectrode was characterized by the SEM/EDS, FTIR, XRD, and UV-Vis Spectrophotometer analyses.

Results: The EDS analysis confirmed the presence of titanium and oxygen in the FTO/ Anodized TiO2 photoelectrode. The XRD results showed that all the peaks of the produced FTO/ Anodic TiO2 were associated with the anatase phase of TiO2. According to the FTIR spectroscopy, the functional groups of the anodized TiO2 were obtained for the FTO/ Anodized TiO2. The electrocatalytic, photocatalytic, and photoelectrocatalytic degradation experiments were performed with the degradation of the dye solution of MB on the FTO/ Anodic TiO2 photoelectrode, and the rates of dye degradation were determined as 17.12%, 64.67%, and 82.12%, respectively.

Conclusion: This study showed that the methylene blue dye of FTO/ Anodic TiO2 is a suitable photoelectrode for electrocatalytic, photocatalytic, and photoelectrocatalytic degradation.

Keywords: Anodization, electrocatalytic, FTO, photocatalytic, photoelectrocatalytic, magnetic sputtering, methylene blue, TiO2.

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